Name | (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) |
Synonyms | Trost (naphthyl) ligand (R,R)-TROST LIGAND(NAPHTHYL) (R,R)-DACH-naphthyl Trost ligand Diaminocyclohexanebisdiphenylphosphinonaph N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphino-1-naphthoyl) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand |
CAS | 174810-09-4 |
InChIKey | VXFKMKXTPXVEMU-AWSIMMLFSA-N |
Molecular Formula | C52H44N2O2P2 |
Molar Mass | 790.87 |
Melting Point | 224-231°C |
Specific Rotation(α) | 69o (C=1 IN METHANOL) |
Appearance | Powder |
Color | off-white |
pKa | 13.43±0.40(Predicted) |
Storage Condition | 2-8℃ |
Sensitive | Easily absorbing moisture |
MDL | MFCD02684551 |
Use | Ligands for asymmetric allyl alkylation reactions |
Hazard Symbols | Xi - Irritant |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
WGK Germany | 3 |
Use | (1R,2R)-( )-1, 2-diaminocyclohexane-N,N'-bis (2-Phenylphosphone-1-naphthalene acyl) is an organic phosphine ligand, commonly used in transition metal catalytic reactions. Ligands for asymmetric allylation reaction |